Taiyou TSUTSUMI (Graduate School of Engineering) paper has been accepted for The Journal of Organic Chemistry.
Congratulations!
Authors
Taiyou Tsutsumi, Takanori Iwasaki, Soji Shimizu
Affiliation
Graduate School of Engineering, Department of Applied Chemistry
Manuscript Title
High-Yielding, Scalable Synthesis of 5,15-Dioxaporphyrin
Abstract
5,15-Dioxaporphyrin (DOP) is a stable 20π antiaromatic molecule with potential for investigating properties arising from antiaromaticity. However, low yields in large-scale synthesis combined with tedious workup procedures have impeded further development of DOP chemistry. Here, we established a high-yielding, scalable synthesis by modifying the concentrations, oxime reagents, reaction time, and solvents. In addition to the reasonable substrate scope, this improved method also enabled the first synthesis of a palladium complex of DOP.
Journal name
The Journal of Organic Chemistry
Relevant SDGs
SDGs 9(Industry, Innovation, Technology and Infrastructure) ,SDGS 12 (Responsible consumption and production)
Comments
I’m so glad the paper was accepted.
